Advanced Quantum Theory
summer term 2023
Lecturer: Haverkort
Link to LSF
53 participants
Lecturer: Haverkort
Link to LSF
53 participants
In this lecture we will discuss the quantum theory of matter and light. We will start by introducing the Dirac equation. After we discuss the basic ideas how Dirac came to introduce this equation and show that the equation makes sence, we will look at the soltion of the hydrogen atom. If we include the electro magnetic field into the Dirac equation we find that the eigen-states are mixed states with different photon number. This leads to the Lamb shift.
We will investigate the interaction between light and matter in more detail by looking at the example of an hydrogen atom in an oscillating external electromagnetic field. If the atom starts in the ground-state then the light field can excite the atom. If the energy of the photons is equal to the energy of an excited state in the atom the transition rate is given by Fermi's golden rule, which we will derive. Experimentally atoms also absorb and scatter photons whose energy does not correspond exactly to the energy differences between eigenstates. This effect can be understood with response theory. We will compare the classical response functions to the onces obtained in quantum mechanics. The later are known as Kubo's formula. Kubo's results will be generalised and we will introduce the concept of Feynman diagrams and self energy.
The theoretical tools introduced in this lecture will be applied to one electron atoms (hydrogen) in the relativistic (Dirac equation) and non-relativistic limit (Schrödinger equation) as well as to multi-electron systems. For many electron systems we will discuss concepts like entanglement and correlations as well as quantum fluctuations. The later will be compared to temperature fluctuations.
The module consists of one lecture per week and a biweekly tutorial session. At the end of the semester there will be a written examination.
Exercise sheets
Material
Script chapter 1 to ..., available as background information
- Quantum_Physics_24_06_2023.pdf
- Quantum_Physics_16_04_2023.pdf
Script per chapter, will be updated during the lecture
- Quantum_Physics_Chapter_11_partial_16_04_2023.pdf
Powerpoint used during the lecture
- Lecture_01.pptx
- Lecture_02.pptx
- Radial_functions_Dirac_h_atom.pdf
- Lamb_shift.pdf
- Response_Theory_hydrogen_atom.pptx
Mathematica Notebook used during the lecture
- Radial functions.nb
- hydrogen_experimental_energies.nb
- hydrogen_experimental_energies
- 01 Classical Harmonic Oscillator.nb
Additional textbooks
- Most books go beyond the topic of the Lecture. The books on atomic physics start roughly where the lecture stops. If you do want to do high precision tests on atoms of physics beyond the standard model or want to understand realistic correlated materials including several battery and solar cell materials, these are highly needed back-ground works.
Related to many-body methods
- Jochem Schirmer Many-Body Methods for Atoms, Molecules and Clusters. Available via HEIDI
- Richard D. Mattuck A Guide to Feynman diagrams in the Many-Body Problem Dover Science Books 2nd Edition
Related to atomic physics
- Robert D. Cowan The Theory of Atomic Structure and Spectra University of California Press
- Zenonas Rudzikas Theoretical Atomic Spectroscopy HEIDI or Cambridge Monographcs on Atomic, Molecular and Chemical Physics
Minimal mathematical background
- Jänich Analysis für Physiker und Ingenieure Springer Lehrbuch
Original Literature
- Here some links to original literature on quantum mechanics. You do not need to read these papers. I provide them for completeness and for those who want to have a look at them. Some are still very good to read, many are original, but clearly dated in the formulation used.
- 1789_Lavoisier_Elements_of_Chemistry.pdf
- 1789_Lavoisier_Traite__e_le_mentaire_de_chimie_pre_sente_.pdf
- 1808_Dalton_A_new_system_of_chemical_philosophy.pdf
- 1860_Kirchhoff_Ueber_das_Verhaeltniss_zwischen_dem_Emissionsvermoegen_und_dem_Absorptionsvermoegen_der_Koerper_fuer_Waerme_und_Licht.pdf
- 1879_Liveing_and_Dewar_On_the_spectra_of_Sodium_and_Potassium.pdf
- 1879_Stefan_Ueber_die_Beziehung_zwishen_der_Waermestrahlung_und_der_Temperatur.pdf
- 1884_Boltzmann_Ableitung_des_Stefansschen_Gesetzes__betreffend_die_Abhaengigkeit_der_Waermestrahlung_von_der_Temperatur_aus_der_electromagnetischen_Lichttheory.pdf
- 1885_Balmer_Notiz_uber_die_Spectrallinien_des_Wasserstoffs.pdf
- 1887_Hertz_Ueber_einen_Einfluss_des_ultravioletten_Lichtes_auf_die_electrische_Entladung.pdf
- 1890_Rydberg_On_the_structure_of_the_line-spectra_of_the_chemical_elements.pdf
- 1890_Rydberg_On_the_structure_of_the_line_spectra_of_the_chemical_elements.pdf
- 1896_Roentgen_On_a_new_kind_of_rays.pdf
- 1897_Lummer_Pringsheim_Die_Strahlung_eines_schwarzen_Koerpers_zwischen_100_und_1300_C.pdf
- 1897_Thomson_Cathode_Rays.pdf
- 1897_Wien_On_the_division_of_energy_in_the_emission_spectrum_of_a_black_body.pdf
- 1897_Zeeman_On_the_influence_of_magnetism_on_the_nature_of_the_light_emitted_by_a_substance.pdf
- 1899_Preston_Radiation_Phenomena_in_the_Magnetic_Field.pdf
- 1900_Planck_Entropie_und_Temperatur_strahlender_Waerme.pdf
- 1900_Planck_Ueber_eine_Verbesserung_der_Wienschen_Spectralgeichung.pdf
- 1900_Planck_Ueber_irreversible_Strahlungsvorgaenge.pdf
- 1900_Planck_Zur_Theory_des_Gesetzes_der_Energieverteilung_im_Normalspectrum.pdf
- 1900_Rayleigh_LIII_Remarks_upon_the_law_of_complete_radiation.pdf
- 1901_Lummer_Pringsheim_Kritisches_zur_schwarzen_Strahlung.pdf
- 1901_Planck_Ueber_das_Gesetz_der_Energieverteilung_im_Normalspectrum.pdf
- 1905_Einstein_Ueber_einen_die_Erzeugung_und_Verwandlung_des_Lichtes_betreffenden_heuristischen_Gesichtspunkt.pdf
- 1905_Jeans_A_Comparison_between_Two_Theories_of_Radiation.pdf
- 1905_Jeans_XI_On_the_partition_of_energy_between_matter_and_aether.pdf
- 1905_Nernst_Ueber_die_Berechnung_chemischer_Gleichgewichte_aus_thermischen_Messungen.pdf
- 1906_Einstein_Zur_theory_der_Lichterzeugung_und_Lichtabsorption.pdf
- 1906_Thomson_On_the_number_of_corpuscles_in_an_atom.pdf
- 1907_Einstein_Die_Plancksche_Theorie_der_Strahlung_und_die_Theorie_der_specifischen_Waerme.pdf
- 1909_Geiger_Marsden_On_a_diffuse_reflection_of_the_alpha-particles.pdf
- 1910_Geiger_The_Scattering_of_the_alpha-Particles_by_Matter.pdf
- 1911_Rutherford_The_scattering_of_alpha_and_beta_particles_by_matter_and_the_structure_of_the_atom.pdf
- 1912_Debye_Zur_Theory_der_specifischen_Waermen.pdf
- 1913_Bohr_On_the_constitution_of_atoms_and_molecules.pdf
- 1913_Bragg_The_reflection_of_X-rays_by_Crystals.pdf
- 1914_Millikan_A_direct_determination_of_h.pdf
- 1915_Einstein_de_Haas_Experimental_proof_of_the_existence_of_Ampere_s_molecular_currents.pdf
- 1915_Wilson_The_quantum_theory_of_radiation_and_line_spectra.pdf
- 1918_Neuther_Invariante_Variationsprobleme.pdf
- 1918_Noether_Invarianten_beliebiger_Differentialausdruecke.pdf
- 1920_Planck_-_Nobel_Lecture_-_The_Genesis_and_Present_State_of_Development_of_the_Quantum_Theory.pdf
- 1920_Planck_-_Nobel_Lecture_-_The_Genesis_and_Present_State_of_Development_of_the_Quantum_Theory_published_in_1922.pdf
- 1921_Stern_Ein_weg_zur_experimentellen_pruefung_der_richtungsquantlung_im_Magnetfeld.pdf
- 1921_Stern_Gerlach_Der_experimentelle_Nachweis_des_magnetischen_Moments_des_Silberatoms_.pdf
- 1922_Stern_Gerlach_Das_magnetische_Moment_des_Silberatoms.pdf
- 1922_Stern_Gerlach_Der_experimentelle_Nachweis_der_Richtungsquantelung_im_Magnetfeld.pdf
- 1923_Compton_A_Quantum_Theory_of_the_Scattering_of_X-rays_by_Light_Elements.pdf
- 1924_De_Broglie_A_tentative_theory_of_light_quanta.pdf
- 1924_De_Broglie_PhD_thesis_En.pdf
- 1924_De_Broglie_PhD_thesis_Fr.pdf
- 1925_Born_Jordan_Zur_Quantenmechanik.pdf
- 1925_Heisenberg_Uber_quantentehoretische_Umdeutung_kinematischer_und_mechanischer_Beziehungen.pdf
- 1925_Pauli_Ueber_den_Einfluss_der_Geschwindigkeitsabhaengigkeit_der_Elektronenmasse_auf_den_Zeemaneffekt.pdf
- 1925_Pauli_Ueber_den_Zusammenhang_des_Abschlusses_der_Elektronengruppen_im_Atom_mit_der_Komplexstrukture_der_Spektren.pdf
- 1925_Uhlenbeck_Goudsmit_Ersetzung_der_Hypothese_vom_unmechanischen_Zwang_durch_eine_Forderung_bezu_glich_des_inneren_Verhaltens_jedes_einzelnen_Elektrons.pdf
- 1926_Born_Heisenberg_Jordan_Zur_Quantenmechanik_II.pdf
- 1926_Born_Quantenmechanik_Der_Stossvorgaenge.pdf
- 1926_Dirac_On_the_Theory_of_Quantum_Mechanics.pdf
- 1926_Gordon_Der_Compton_effekt_nach_der_schroedingerschen_Theory.pdf
- 1926_Newton_The_conservation_of_Photons.pdf
- 1926_Schroedinger_Der_stetige_Uebergang_von_der_Mikro-_zur_Makromechanik.pdf
- 1926_Schroedinger_Quantisierung_als_Eigenwertprobelm_I.pdf
- 1926_Schroedinger_Quantisierung_als_Eigenwertprobelm_II.pdf
- 1926_Schroedinger_Quantisierung_als_Eigenwertprobelm_III.pdf
- 1926_Schroedinger_Quantisierung_als_Eigenwertprobelm_IV.pdf
- 1926_Schroedinger_Ueber_das_Verhaeltnis_der_Heisenberg-Born_Jordanschen_Quantenmechanik_zu_der_meinen.pdf
- 1926_Thomas_The_Motion_of_the_Spinning_Electron.pdf
- 1926_Uhlenbeck_Goudsmit_Spinning_Electrons_and_the_Structure_of_Spectra.pdf
- 1927_Darwin_The_Electron_as_a_Vector_Wave.pdf
- 1927_Kennard_Zur_Quantenmechanik_einfacher_Bewegunstypen.pdf
- 1927_Klein_Elektrodynamik_und_Wellenmechanik_von_Standpunkt_des_Korrespondenzprinzips.pdf
- 1927_Pauli_Zur_Quantenmechanik_des_magnetischen_Elektrons.pdf
- 1927_Thomson_Diffraction_of_Cathode_Rays_by_a_thin_film.pdf
- 1928_Dirac_The_Quantum_Theory_of_the_Electron.pdf
- 1929_Slater_The_Theory_of_Complex_Spectra.pdf
- 1939_Dirac_A_new_notation_for_quantum_mechanics.pdf
- 1943_Planck_Zur_Geschichte_der_Auffindung_des_physikalischen_Wirkunsquantums.pdf
- 1947_Lamb_Retherford_Fine_Structure_of_the_Hydrogen_Atom_by_Microwave_Method.pdf
- 1950_Structure_of_Anthracene.pdf
- 1957_Elektronendichte_in_NaCl.pdf
- 1964_Loewdin_Angular_Momentum_Wavefunctions_Constructed_by_Projector_Operators.pdf_.pdf
- 1968_Calais_Derivation_of_the_Clebsch_Gordan_coefficients_by_means_of_projection.pdf
- 1972_Anderson_More_is_different.pdf
- 1989_Demonstration_of_single-electron_buildup_of_an_interference_pattern.pdf
- 1995_Anderson_Physics_the_opening_to_complexity.pdf
- 2001_Staumann_Schroedingers_Entdeckung_der_Wellenmechanik.pdf
- 2013_Controlled_double-slit_electron_diffraction
- 2013_Controlled_double-slit_electron_diffraction.zip
Practice groups
- Group 1 (Natalia Oreshkina)
13 participants
INF 227 / SR 3.403, Tue 14:15 - 16:00 - Group 2 (Chen Xin)
10 participants
Philos.-weg 12 / kHS, Wed 14:15 - 16:00 - Group 3 (Félix Rose)
20 participants
INF 227 / SR 2.402, Wed 16:15 - 18:00 - Group 4 (Mrinal Sarkar)
10 participants
Philoso.-weg 12 / kHS, Tue 14:15 - 16:00
Material discussed
17.04.2023 | Chapter 11 of the script. Introduction to the Dirac equation. |
24.04.2023 | Chapter 11 of the script. Non-relativistic limit of the Dirac equation. |
1.05.2023 | No Lecture |
8.05.2023 | Chapter 11 of the script. Relativistic solutions to the Dirac equation and introduction to the Lamb shift. |
15.05.2023 | |
22.05.2023 | |
29.05.2023 | No Lecture |
5.06.2023 | |
12.06.2023 | |
19.06.2023 | |
26.06.2023 | Response theory, relation between frequency and time domain. Kramers Kronig relation |
3.07.2023 | Response theory, relation between frequency and time domain. Kramers Kronig relation |
10.07.2023 | Decoherence and quasi-particle lifetime |
17.07.2023 | Free time to study |
24.07.2023 | Exam |
31.07.2023 | Discussion of exam results |
Advanced Quantum Theory
calendar
- The lectures will be on Monday from 14:15 to 16:00 in INF 227 HS2. The first lecture is on Monday the 17th of April.
- The tutorials will be biweekly, starting in the week of the 24th of April.
- I higly recommend you to be present in the lecture hall. For those who can not come we will stream the lectures via Zoom.
- After some time the lectures will apear on Youtube. (We will filter out all voices of students present in the room)
- The exam will be on Monday the 24th of July from 14:15 to 17:00 in INF227 HS2.